Material safety data sheet

Click Bond - CB200 Adhesive - Safety Data Sheet
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY UNDERTAKING
1.2. Relevant identified uses of the substance or mixture and uses advised against For industrial and professional use only. Two component acrylic adhesive. 1.3. Details of the supplier of the safety data sheet CLICK BOND, INC. 2151 LOCKHEED WAY CARSON CITY, NV 89706-0713 U.S.A. Information Telephone: 001-775-885-8000 email: sales@clickbond.com LORD CORPORATION 111 LORD DRIVE CARY, NC 27511-7923 U.S.A. Information Telephone: 001-814-868-0924 email: europemsds@lord.com TRANSPORTATION EMERGENCY: CHEMTEL 24 HOUR EMERGENCY NO.: 800-255-3924 OUTSIDE NORTH AMERICA: 001-813-248-0585 (call collect) NON-TRANSPORTATION EMERGENCY TELEPHONE NO. (USA): 001-800-255-3924 SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture component B: Xn;R22. Carc. Cat. 3;R40. Xi;R36/37/38. R43. F;R11. R52/53. component A: Xi;R36/38. R43. O;R7. N;R51/53. Component B
Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitisation by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Keep container tightly closed and in a well-ventilated place. Keep away from sources of ignition - No smoking. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. CB200 SDS Rev. 0
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Component A
BENZOYL PEROXIDE EPOXY RESIN (Number average MW <= 700) May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Keep container tightly closed in a cool place. Keep away from acids, bases, reducing substances and heavy metals. Wear suitable protective clothing and gloves. Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Contains epoxy constituents. See information supplied by the manufacturer. This product does not contain any PBT or vPvB Substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
1,1'-(p-Tolylimino)dipropan-2-ol
Component B
CAS-No.: 38668-48-3
EC No.: 254-075-1
2-HYDROXYETHYL METHACRYLATE
Component B
CAS-No.: 868-77-9
EC No.: 212-782-2
2-Propenoic acid, 2-methyl-, 2-hydroxyethyl ester, phosphate
Component B
CAS-No.: 52628-03-2
EC No.: 258-053-2
METHACRYLIC ACID
Component B
CAS-No.: 79-41-4
EC No.: 201-204-4
Skin Corr. 1A - H314 STOT Single 3 - H335 CB200 SDS Rev. 0
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METHYL METHACRYLATE
Component B
CAS-No.: 80-62-6
EC No.: 201-297-1
N,N-DIMETHYLANILINE
Component B
CAS-No.: 121-69-7
EC No.: 204-493-5
PHOSPHORIC ACID .%
Component B
CAS-No.: 7664-38-2
EC No.: 231-633-2
ZINC OXIDE
Component B
CAS-No.: 1314-13-2
EC No.: 215-222-5
BENZOYL PEROXIDE
Component A
CAS-No.: 94-36-0
EC No.: 202-327-6
BRANCHED C10-ALKYL BENZOATES
Component A
CAS-No.: 131298-44-7
EC No.: 421-090-1
EPOXY RESIN (Number average MW <= 700)
Component A
CAS-No.: 25068-38-6
EC No.: 500-033-5
The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16. SECTION 4: FIRST AID MEASURES
General Information
Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. NOTE! Keep affected person away from heat, sparks and flames! Inhalation
Move the exposed person to fresh air at once. For breathing difficulties oxygen may be necessary. If breathing stops, provide artificial respiration. Provide rest, warmth and fresh air. Get prompt medical attention. CB200 SDS Rev. 0
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Ingestion
DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Immediately rinse mouth and drink plenty of water (200-300 ml). Get medical attention. Skin Contact
Promptly flush contaminated skin with water. Promptly remove clothing if soaked through and flush the skin with water. Wash skin thoroughly with soap and water. Get medical attention promptly if symptoms occur after washing. Eye Contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention immediately. Continue to rinse for at least 15 minutes. 4.2. Most important symptoms and effects, both acute and delayed General Information
NOTE! Effects may be delayed. Keep affected person under observation. Inhalation
Skin Contact
May cause serious chemical burns to the skin. Eye Contact
May cause severe irritation to eyes and mucous membranes. Causes burns. 4.3. Indication of any immediate medical attention and special treatment needed NOTE! Effects may be delayed. Keep affected person under observation. SECTION 5: FIREFIGHTING MEASURES
Extinguishing Media
Fire can be extinguished using: Foam. Dry chemicals, sand, dolomite etc. Carbon dioxide (CO2). Water spray, fog or mist. 5.2. Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards
FLAMMABLE. Vapours are heavier than air and may spread near ground to sources of ignition. May travel considerable distance to source of ignition and flash back. Closed containers may rupture when exposed to extreme heat. Specific Hazards
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Refer to section 10 of this safety data sheet for more information on hazardous decomposition products. Special Fire Fighting Procedures
Move container from fire area if it can be done without risk. Containers close to fire should be removed or cooled with water. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. Protective Measures In Fire
Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. Do not discharge into drains, water courses or onto the ground. 6.3. Methods and material for containment and cleaning up Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Avoid contact with skin or inhalation of spillage, dust or vapour. Absorb spillage with non-combustible, absorbent material. Collect spillage with non-combustible, absorbent material into suitable containers, seal securely and deliver for disposal according to local regulations. CB200 SDS Rev. 0
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For personal protection, see section 8. For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE
Static electricity and formation of sparks must be prevented. Keep away from heat, sparks and open flame. Use explosion proof electric equipment. Container must be kept tightly closed. Avoid spilling. Avoid contact with skin and eyes. Empty containers should not be re-used. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Do not use in confined spaces without adequate ventilation and/or respirator. Persons susceptible to allergic reactions should not handle this product. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. For maximum shelf life, store in closed original container at temperatures between 4 - 10ºC (see Technical Data Sheet for more product specific storage instructions). Storage Class
Component B
Component A
The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredient Comments
Protective Equipment

Engineering Measures
Explosion-proof general and local exhaust ventilation. Respiratory Equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Chemical respirator with organic vapour cartridge. Hand Protection
Protective gloves must be used if there is a risk of direct contact or splash. Use protective gloves made of: Neoprene. Nitrile. Butyl rubber. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Eye Protection
Use approved safety glasses with side shields. If risk of splashing, wear safety goggles or face shield. Other Protection
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Hygiene Measures
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. Contaminated clothing to be placed in closed container until disposal or decontamination. Warn cleaning personnel of chemical's hazardous properties. CB200 SDS Rev. 0
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties Component B
Component A
SECTION 10: STABILITY AND REACTIVITY
Stable under normal temperature conditions and recommended use. 10.3. Possibility of hazardous reactions Hazardous Polymerisation
Hazardous polymerisation will not occur under normal conditions. Avoid exposure to high temperatures or direct sunlight. Materials To Avoid
Strong alkalis. Strong acids. Strong oxidising substances. Organic peroxides/hydroperoxides. Inorganic peroxides. Amines. Hydroxyl, or active hydrogen compounds. Water, steam, water mixtures. Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Aldehydes. Oxides of: Nitrogen. Phosphorus. SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects Other Health Effects
General Information
The present product is a chemical preparation within the meaning of the REACh Regulation 1907/2006/EC. To avoid testing the product in animal experiments the evaluation is made based on toxicological data and content by weight of the individual ingredients according to 1999/45/EC or analagous evaluations of comparable products. Inhalation
Irritating to respiratory system. May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Ingestion
Harmful if swallowed. Liquid irritates mucous membranes and may cause abdominal pain if swallowed. Skin Contact
May cause sensitisation by skin contact. Irritating to skin. Based on the results of corrosivity testing for classification of dangerous goods, this product, or a comparable formulation would be considered non-corrosive to the skin. Eye Contact
CB200 SDS Rev. 0
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SECTION 12: ECOLOGICAL INFORMATION
Do not empty into drains, soil or bodies of water. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Acute Fish Toxicity
Degradability
Bioaccumulative Potential
Mobility
The product is partly soluble in water. May spread in the aquatic environment. 12.5. Results of PBT and vPvB assessment This product does not contain any PBT or vPvB Substances. SECTION 13: DISPOSAL CONSIDERATIONS
General Information
The valid EEC waste code numbers are not product-related but are largely source-related. The manufacturer is therefore unable to specify EEC waste codes for the articles or products used in the various sectors. These can be requested from the manufacturer. When handling waste, consideration should be made to the safety precautions applying to handling of the product. Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION
General: This product may be shipped as part of 2 component acrylic adhesive kits under UN 3269 POLYESTER RESIN KIT.
Component B
Component A
Component B
Component A
ORGANIC PEROXIDE TYPE E, SOLID (BENZOYL PEROXIDE, EPOXY RESIN (Number average MW <= 700)) CB200 SDS Rev. 0
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Component B
Transport Labels

Component A
Transport Labels
Component B
Component B
Environmentally Hazardous Substance/Marine Pollutant
Component A
Environmentally Hazardous Substance/Marine Pollutant

Component B
CB200 SDS Rev. 0
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Component A
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. Water Hazard Classification
No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION
Information Sources
Dangerous Properties of Industrial Materials Report, N.Sax et.al. The Merck Index, 11. edition, 1989. Safety Data Sheets, Misc. manufacturers. GESTIS-database on hazardous substances (www.dguv.de/bgia/gestis-database). Revision Comments
Issued By
Revision Date
Revision
Supersedes Date
Risk Phrases In Full
Harmful in contact with skin and if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitisation by skin contact. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R25 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Extreme risk of explosion by shock, friction, fire or other sources of ignition. CB200 SDS Rev. 0
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Hazard Statements In Full
Causes severe skin burns and eye damage. Harmful to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Very toxic to aquatic life with long lasting effects. DISCLAIMER: The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of
handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this
material. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations.
CB200 SDS Rev. 0
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Source: http://www.viba.nl/files/msds/vib0001426.pdf