Chemwatch msds 5099-14

MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 1 of 11
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
SYNONYMS
PRODUCT USE
SUPPLIER
Company: Mapei Australia P/L
Address:
12 Parkview Drive
Archerfield
QLD, 4108
AUS
Telephone: +61 7 3276 5000
Fax: +61 7 3276 5076
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the
Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
Causes burns.
Risk of serious damage to eyes.
May cause SENSITISATION by inhalation.
Cumulative effects may result following exposure*.
Possible skin sensitiser*.
* (limited evidence).
Keep locked up.
Avoid contact with eyes.
Wear suitable protective clothing.
To clean the floor and all objects contaminated by this material, use water and detergent.
Take off immediately all contaminated clothing.
In case of accident or if you feel unwell IMMEDIATELY contact Doctor or Poisons Information Centre (show label if possible).
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 2 of 11
Section 4 - FIRST AID MEASURES
SWALLOWED
• For advice, contact a Poisons Information Centre or a doctor at once.
• Urgent hospital treatment is likely to be needed.
• If swallowed do NOT induce vomiting.
• If vomiting occurs, lean patient forward or place on left side (head-downposition, if possible) to maintain open airway and prevent aspiration.
• Observe the patient carefully.
• Never give liquid to a person showing signs of being sleepy or with reducedawareness; i.e. becoming unconscious.
• Give water to rinse out mouth, then provide liquid slowly and as much ascasualty can comfortably drink.
• Transport to hospital or doctor without delay.
If this product comes in contact with the eyes:• Immediately hold eyelids apart and flush the eye continuously with runningwater.
• Ensure complete irrigation of the eye by keeping eyelids apart and away fromeye and moving the eyelids by occasionally lifting the upper and lower lids.
• Continue flushing until advised to stop by the Poisons Information Centre or adoctor, or for at least 15 minutes.
• Transport to hospital or doctor without delay.
• Removal of contact lenses after an eye injury should only be undertaken byskilled personnel.
If skin or hair contact occurs:• Immediately flush body and clothes with large amounts of water, using safetyshower if available.
• Quickly remove all contaminated clothing, including footwear.
• Wash skin and hair with running water. Continue flushing with water untiladvised to stop by the Poisons Information Centre.
• Transport to hospital, or doctor.
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed,where possible, prior to initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand valveresuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR ifnecessary.
• Transport to hospital, or doctor, without delay.
NOTES TO PHYSICIAN
For sub-chronic and chronic exposures to isocyanates:• This material may be a potent pulmonary sensitiser which causes bronchospasmeven in patients without prior airway hyperreactivity.
• Clinical symptoms of exposure involve mucosal irritation of respiratory andgastrointestinal tracts.
• Conjunctival irritation, skin inflammation (erythema, pain vesiculation) andgastrointestinal disturbances occur soon after exposure.
• Pulmonary symptoms include cough, burning, substernal pain and dyspnoea.
• Some cross-sensitivity occurs between different isocyanates.
• Noncardiogenic pulmonary edema and bronchospasm are the most seriousconsequences of exposure. Markedly symptomatic patients should receive oxygen,ventilatory support and an intravenous line.
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 3 of 11
Section 4 - FIRST AID MEASURES
• Treatment for asthma includes inhaled sympathomimetics (epinephrine[adrenalin], terbutaline) and steroids.
• Activated charcoal (1 g/kg) and a cathartic (sorbitol, magnesium citrate) maybe useful for ingestion.
• Mydriatics, systemic analgesics and topical antibiotics (Sulamyd) may be usedfor corneal abrasions.
• There is no effective therapy for sensitised workers.
[Ellenhorn and Barceloux; Medical Toxicology]NOTE: Isocyanates cause airway restriction in naive individuals with the degreeof response dependant on the concentration and duration of exposure. They inducesmooth muscle contraction which leads to bronchoconstrictive episodes. Acutechanges in lung function, such as decreased FEV1, may not represent sensitivity.
[Karol & Jin, Frontiers in Molecular Toxicology, pp 56-61, 1992].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
• Carbon dioxide.
• Water spray or fog - Large fires only.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves.
• Prevent, by any means available, spillage from entering drains or watercourses.
• Use water delivered as a fine spray to control fire and cool adjacent area.
• DO NOT approach containers suspected to be hot.
• Cool fire exposed containers with water spray from a protected location.
• If safe to do so, remove containers from path of fire.
• Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
• Combustible.
• Slight fire hazard when exposed to heat or flame.
• Heating may cause expansion or decomposition leading to violent rupture ofcontainers.
• On combustion, may emit toxic fumes of carbon monoxide (CO).
• May emit acrid smoke.
• Mists containing combustible materials may be explosive.
Combustion products include.
nitrogen oxides (NOx).
May emit corrosive fumes.
FIRE INCOMPATIBILITY
None known.
Personal Protective Equipment
PERSONAL PROTECTION EQUIPMENTGas tight chemical resistant suit.
Limit exposure duration to 1 BA set - 30 mins.
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 4 of 11
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
• Clean up all spills immediately.
• Avoid contact with skin and eyes.
• Wear impervious gloves and safety goggles.
• Trowel up/scrape up.
• Place spilled material in clean, dry, sealed container.
• Flush spill area with water.
MAJOR SPILLS
Minor hazard.
• Clear area of personnel.
• Alert Fire Brigade and tell them location and nature of hazard.
• Control personal contact by using protective equipment as required.
• Prevent spillage from entering drains or water ways.
• Contain spill with sand, earth or vermiculite.
• Collect recoverable product into labelled containers for recycling.
• Absorb remaining product with sand, earth or vermiculite and place inappropriate containers for disposal.
• Wash area and prevent runoff into drains or waterways.
• If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
irreversible or other serious effects or symptoms which couldimpair an individual's ability to take protective action is: other than mild, transient adverse effectswithout perceiving a clearly defined odour is: The threshold concentration below which most people.
will experience no appreciable risk of health effects: American Industrial Hygiene Association (AIHA) Ingredients considered according exceed the following cutoffs where percentage is percentage of ingredient found in the mixture Personal Protective Equipment advice is contained in Section 8 of the MSDS.
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 5 of 11
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
• Avoid all personal contact, including inhalation.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• Prevent concentration in hollows and sumps.
• DO NOT enter confined spaces until atmosphere has been checked.
• DO NOT allow material to contact humans, exposed food or food utensils.
• Avoid contact with incompatible materials.
• When handling, DO NOT eat, drink or smoke.
• Keep containers securely sealed when not in use.
• Avoid physical damage to containers.
• Always wash hands with soap and water after handling.
• Work clothes should be laundered separately. Launder contaminated clothingbefore re-use.
• Use good occupational work practice.
• Observe manufacturer's storing and handling recommendations.
• Atmosphere should be regularly checked against established exposure standardsto ensure safe working conditions are maintained.
SUITABLE CONTAINER
• Metal can or drum• Packaging as recommended by manufacturer.
• Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
STORAGE REQUIREMENTS
• Store in original containers.
• Keep containers securely sealed.
• Store in a cool, dry, well-ventilated area.
• Store away from incompatible materials and foodstuff containers.
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source
No data available for 4,4'-diphenylmethane diisocyanate (MDI) as (CAS: 26447-40-5 )Not available. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust componentsand concentration: "Worst Case" computer-aided prediction of spray/ mist or fume/ dust componentsand concentration:Composite Exposure Standard for Mixture (TWA) :0.02 mg/m³.
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 6 of 11
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust componentsand concentration:Composite Exposure Standard for Mixture (TWA) (mg/m³):Operations which produce a spray/mist or fume/dust, introduce particulates tothe breathing zone.
If the breathing zone concentration of ANY of the components listed below isexceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m³ Mixture Conc (%).
INGREDIENT DATA
The TLV-TWA is thought to be protective against undue irritation and isanalogous to that recommended for sodium hydroxide.
Some jurisdictions require that health surveillance be conducted onoccupationally exposed workers. This should emphasise:· demography, occupational and medical history and health advice· completion of a standardised respiratory questionnaire· physical examination of the respiratory system and skin· standardised respiratory function tests such as FEV1, FVC and FEV1/FVC.
Odour Threshold Value: 0.39 ppmMean MDI exposures of less than 0.003 ppm appear to have no acute orchronic effect on pulmonary function.
MDI produces identical toxicological responses to those produced by TDIand the recommended TLV-TWA is identical for the two isocyanates. Exposureat or below the recommended value is thought to protect the worker againstpulmonary function decrements as well as to minimise the potential forrespiratory tract sensitisation. Individuals who may be hypersusceptibleor otherwise unusually responsive to exposure to certain industrialchemicals may not adequately protected from adverse health effects causedby MDI at the recommended TLV-TWA. Ceiling values recommended by NIOSHand OSHA are synonymous with normal excursions allowable for exposures tothe TLV-TWA (in excess of 3 x TLV-TWA for no more than a total of30 minutes during a work day but in any case not exceeding 5 x TLV-TWA).
PERSONAL PROTECTION
• Chemical goggles.
• Full face shield may be required for supplementary but never for primaryprotection of eyes• Contact lenses may pose a special hazard; soft contact lenses may absorb andconcentrate irritants. A written policy document, describing the wearing of lensor restrictions on use, should be created for each workplace or task. Thisshould include a review of lens absorption and adsorption for the class ofchemicals in use and an account of injury experience. Medical and first-aidpersonnel should be trained in their removal and suitable equipment should bereadily available. In the event of chemical exposure, begin eye irrigationimmediately and remove contact lens as soon as practicable. Lens should beremoved at the first signs of eye redness or irritation - lens should be removedin a clean environment only after workers have washed hands thoroughly. [CDCNIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 7 of 11
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Wear safety footwear or safety gumboots, eg. Rubber.
• Overalls.
• P.V.C. apron.
• Barrier cream.
• Skin cleansing cream.
• Eye wash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level ofbreathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside themask) may also be important.
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of usedetermine the type of personal protective equipment required.
For further information consult site specific CHEMWATCH data (ifavailable), or your Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaustventilation may be required in special circumstances. If risk of overexposureexists, wear approved respirator. Supplied-air type respirator may be requiredin special circumstances. Correct fit is essential to ensure adequateprotection. Provide adequate ventilation in warehouses and enclosed storageareas. Air contaminants generated in the workplace possess varying "escape"velocities which, in turn, determine the "capture velocities" of freshcirculating air required to effectively remove the contaminant.
evaporating from tank (in still air).
aerosols, fumes from pouring operations, intermittent containerfilling, low speed conveyer transfers,welding, spray drift, plating acidfumes, pickling (released at lowvelocity into zone of activegeneration)direct spray, spray painting in shallow booths, drum filling, conveyer loading,crusher dusts, gas discharge (activegeneration into zone of rapid airmotion)grinding, abrasive blasting, tumbling, high speed wheel generated dusts(released at high initial velocity intozone of very high rapid air motion) continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 8 of 11
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Within each range the appropriate value depends on: favourable to capture2: Contaminants of low toxicity or of nuisance value only.
3: Intermittent, low production.
Simple theory shows that air velocity falls rapidly with distance away from theopening of a simple extraction pipe. Velocity generally decreases with thesquare of distance from the extraction point (in simple cases). Therefore theair speed at the extraction point should be adjusted, accordingly, afterreference to distance from the contaminating source. The air velocity at theextraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) forextraction of solvents generated in a tank 2 meters distant from the extractionpoint. Other mechanical considerations, producing performance deficits withinthe extraction apparatus, make it essential that theoretical air velocities aremultiplied by factors of 10 or more when extraction systems are installed orused.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Beige paste with a typical odour; partially miscible with water.
PHYSICAL PROPERTIES
Solubility in water (g/L): Partly Miscible Relative Vapour Density (air=1): Not Available Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Product is considered stable and hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 9 of 11
Section 11 - TOXICOLOGICAL INFORMATION
SWALLOWED
The material can produce chemical burns within the oral cavity andgastrointestinal tract following ingestion.
The material has NOT been classified by EC Directives or other classificationsystems as "harmful by ingestion". This is because of the lack of corroboratinganimal or human evidence. The material may still be damaging to the health ofthe individual, following ingestion, especially where pre-existing organ (eg.
liver, kidney) damage is evident. Present definitions of harmful or toxicsubstances are generally based on doses producing mortality rather than thoseproducing morbidity (disease, ill-health). Gastrointestinal tract discomfort mayproduce nausea and vomiting. In an occupational setting however, ingestion ofinsignificant quantities is not thought to be cause for concern.
The material can produce chemical burns to the eye following direct contact.
Vapours or mists may be extremely irritating.
If applied to the eyes, this material causes severe eye damage.
The material can produce chemical burns following direct contactwith the skin.
Skin contact is not thought to have harmful health effects (as classified underEC Directives); the material may still produce health damage following entrythrough wounds, lesions or abrasions.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,may produce systemic injury with harmful effects. Examine the skin prior to theuse of the material and ensure that any external damage is suitably protected.
The material can cause respiratory irritation in some persons. The body'sresponse to such irritation can cause further lung damage.
CHRONIC HEALTH EFFECTS
Asthma-like symptoms may continue for months or even years after exposure to thematerial ceases. This may be due to a non-allergenic condition known as reactiveairways dysfunction syndrome (RADS) which can occur following exposure to highlevels of highly irritating compound. Key criteria for the diagnosis of RADSinclude the absence of preceding respiratory disease, in a non-atopicindividual, with abrupt onset of persistent asthma-like symptoms within minutesto hours of a documented exposure to the irritant. A reversible airflow pattern,on spirometry, with the presence of moderate to severe bronchial hyperreactivityon methacholine challenge testing and the lack of minimal lymphocyticinflammation, without eosinophilia, have also been included in the criteria fordiagnosis of RADS. RADS (or asthma) following an irritating inhalation is aninfrequent disorder with rates related to the concentration of and duration ofexposure to the irritating substance. Industrial bronchitis, on the other hand,is a disorder that occurs as result of exposure due to high concentrations ofirritating substance (often particulate in nature) and is completely reversibleafter exposure ceases. The disorder is characterised by dyspnea, cough andmucous production. Inhaling this product is more likely to cause a sensitisationreaction in some persons compared to the general population. Respiratorysensitisation may result in allergic/asthma like responses; from coughing andminor breathing difficulties to bronchitis with wheezing, gasping. Sensitisationmay give severe responses to very low levels of exposure, i.e. hypersensitivity.
Sensitised persons should not be allowed to work in situations where exposuremay occur. Isocyanate vapours are irritating to the airways and can cause theirinflammation, with wheezing, gasping, severe distress, even loss ofconsciousness and fluid in the lungs. Nervous system symptoms that may occurinclude headache, sleep disturbance, euphoria, inco-ordination, anxiety,depression and paranoia. Digestive effects include nausea and vomiting.
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 10 of 11
Section 11 - TOXICOLOGICAL INFORMATION
Breathing difficulties may occur unpredictably after a period of tolerance andafter skin contact. Allergic inflammation of the skin can occur, with rash,itching, blistering, and swelling of the hands and feet. Sensitive people canreact to very low levels and should not be exposed to this material.
TOXICITY AND IRRITATION
None assigned. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
CALCIUM OXIDE:Not available. Refer to individual constituents.
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI):TOXICITY Inhalation (human) TCLo: 0.13 ppm/30 mins Eye(rabbit): 0.10 mg ModerateInhalation (rat) LC50: 178 mg/m3/4h The substance is classified by IARC as Group 3:NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows: 4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI):Half-life Soil - High (hours): 24Half-life Soil - Low (hours): 6Half-life Air - High (hours): 5.8Half-life Air - Low (hours): 0.58Half-life Surface water - High (hours): 24Half-life Surface water - Low (hours): 6Half-life Ground water - High (hours): 24Half-life Ground water - Low (hours): 6Aqueous biodegradation - Aerobic - High (hours): 672Aqueous biodegradation - Aerobic - Low (hours): 168Aqueous biodegradation - Anaerobic - High (hours): 2688Aqueous biodegradation - Anaerobic - Low (hours): 672Photooxidation half-life air - High (hours): 5.8Photooxidation half-life air - Low (hours): 0.58First order hydrolysis half-life (hours): 12 nbsp;log#nbsp;Kow#nbsp;#nbsp;:#nbsp;1.9Toxicity Fish: LC50(96)95.24-134.37mg/L Section 13 - DISPOSAL CONSIDERATIONS
• Consult manufacturer for recycling options and recycle where possible .
• Consult State Land Waste Management Authority for disposal.
• Incinerate residue at an approved site.
• Recycle containers if possible, or dispose of in an authorised landfill.
Puncture containers to prevent re-use and bury at an authorised landfill.
continued.
MAPEI ULTRA/BOND P990 1 K BEIGE
Chemwatch Material Safety Data Sheet
CHEMWATCH 5099-14
Issue Date: Mon 22-Dec-2003
CD 2005/3 Page 11 of 11
Section 14 - TRANSPORTATION INFORMATION
Dangerous Goods Class: NoneSubrisk: NoneUN/NA Number: NonePacking Group: NoneLabels Required: Additional Shipping Information: International Transport Regulations: IMO Dangerous Goods class: None IMO Packing group: NoneIATA Dangerous goods class: NoneCargo Instructions: Cargo Max: Passenger Instructions: Passenger Max: Special Provisions: None, None Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
REGULATIONS
calcium oxide (CAS: 1305-78-8) is found on the following regulatory lists:Australian Inventory of Chemical Substances (AICS)Australia High Volume Industrial Chemical List (HVICL) 4,4'-diphenylmethane diisocyanate (MDI) (CAS: 101-68-8) is found on thefollowing regulatory lists:Australian Inventory of Chemical Substances (AICS)Australian Poisons ScheduleAustralia High Volume Industrial Chemical List (HVICL)Australia Tasmania Hazardous Substances Requiring Health SurveillanceAustralia New South Wales Hazardous Substances Requiring Health SurveillanceAustralia Western Australia Hazardous Substances Requiring Health SurveillanceAustralia Occupational Health and Safety (Commonwealth Employment) (NationalStandards) Regulations 1994 - Hazardous Substances Requiring Health SurveillanceAustralia Hazardous Substances Requiring Health Surveillance No data available for 4,4'-diphenylmethane diisocyanate (MDI) as CAS: 26447-40-5.
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes ofprivate study, research, review or criticism, as permitted under the CopyrightAct, no part may be reproduced by any process without written permission fromCHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Mon 22-Dec-2003Print Date: Tue 15-Nov-2005

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