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Product Name
RAID COMMERCIAL INSECTICIDE RESIDUAL SURFACE SPRAY
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Supplier Name
DIVERSEY AUSTRALIA PTY. LIMITED
29 Chifley St, Smithfield, NSW, AUSTRALIA, 2164 Telephone
Emergency
Synonym(s)
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
RISK PHRASES
R65
Harmful: May cause lung damage if swallowed.
SAFETY PHRASES
S2
Keep container in a well ventilated place.
Keep away from sources of ignition - No smoking.
Do not breathe gas/fumes/vapour/spray (where applicable).
If swallowed, do not induce vomiting; seek medical advice immediately and show this container or label.
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
Subsidiary Risk(s) None Allocated
Packing Group
Hazchem Code
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient
Product Name
RAID COMMERCIAL INSECTICIDE RESIDUAL SURFACE SPRAY
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by aPoisons Information Centre, a doctor, or for at least 15 minutes.
Inhalation
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continueflushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion
For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed,do not induce vomiting. Ingestion is considered unlikely due to product form.
Special treatment Treat symptomatically.
First aid facilities
Eye wash facilities and safety shower should be available.
5. FIRE FIGHTING MEASURES
Special hazards
Highly flammable. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Vapourmay form explosive mixtures with air. Eliminate all ignition sources including cigarettes, open flames, sparkproducing switches/tools, heaters, naked lights, pilot lights, mobile phones etc. when handling. Aerosol cans mayexplode when heated above 50°C.
Advice for
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind firefighters
and notify those downwind of hazard. Wear full protective equipment including Self Contained BreathingApparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.
Extinguishing
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.
Hazchem Code
6. ACCIDENTAL RELEASE MEASURES
Spillage

If aerosol can damaged or leaking, clear area of all unprotected personnel and ventilate. Use personal protectiveequipment. Clear area of all unprotected personnel. Collect and allow to discharge outdoors. Contain spillage,then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and placein suitable containers for disposal.
7. STORAGE AND HANDLING
Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, alkalis, heat or ignition sourcesand foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when notin use. Check regularly for leaks or spills. Large storage areas should have appropriate fire protection systems. Donot allow product to freeze.
Precautions for
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin safe handling
contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating,drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
Exposure Stds
Ingredient
Reference
Biological Limits
Engineering
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is Controls
recommended. Flammable/explosive vapours may accumulate in poorly ventilated areas. Vapours are heavierthan air and may travel some distance to an ignition source and flash back. Maintain vapour levels below therecommended exposure standard.
Personal Protective Equipment is not required under normal conditions of use.Where an inhalation risk exists,wear: a Type A-Class P1 (Organic gases/vapours and Particulate) respirator. With prolonged use, wear: splash-proof goggles, PVC or rubber gloves and safety glasses.
Product Name
RAID COMMERCIAL INSECTICIDE RESIDUAL SURFACE SPRAY
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Solubility (water)
Specific Gravity
% Volatiles
Vapour Pressure
Flammability
Vapour Density
Flash Point
Boiling Point
Upper Explosion Limit
Melting Point
Lower Explosion Limit
Evaporation Rate
Autoignition Temperature
Decomposition Temperature NOT AVAILABLE
Partition Coefficient
Viscosity
10. STABILITY AND REACTIVITY
Chemical stability

Stable under recommended conditions of storage.
Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
Material to Avoid
Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), alkalis (eg. hydroxides), heatand ignition sources.
Hazardous
May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition.
Decomposition
Products

Hazardous Reactions
Polymerization is not expected to occur.
11. TOXICOLOGICAL INFORMATION
Health hazard
This product has the potential to cause adverse health effects with over exposure. Use safe work practices to avoid eye or skin contact and inhalation.
Contact may result in irritation, lacrimation, pain and redness.
Inhalation
Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.
Contact may result in irritation, redness, rash and dermatitis. May cause sensitisation by skin contact.
Ingestion
Toxicity Data
PERMETHRIN (52645-53-1) LC50 (Inhalation): 485 mg/m³ (rat) LD50 (Ingestion): 383 mg/kg (rat) LD50 (Intraperitoneal): 429 mg/kg (mouse) LD50 (Intravenous): 31 mg/kg (mouse) LD50 (Skin): 1750 mg/kg (rat) LD50 (Subcutaneous): 6600 mg/kg (rat)TETRAMETHRIN (7696-12-0) LC50 (Inhalation): 2 g/m³ (mouse) LD50 (Ingestion): 1000 mg/kg (mouse) LD50 (Intraperitoneal): 527 mg/kg (mouse) LD50 (Intravenous): 3500 ug/kg (rat) LD50 (Skin): 2500 ug/kg (rat) LD50 (Subcutaneous): 1950 mg/kg (mouse) 12. ECOLOGICAL INFORMATION
Other adverse

Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriate measures are taken to prevent this product from entering the environment.
13. DISPOSAL CONSIDERATIONS
Waste disposal
For small amounts absorb contents with sand or similar and dispose of to an approved landfill site. Do notpuncture or incinerate aerosol cans. Contact the manufacturer for additional information.
Legislation
Dispose of in accordance with relevant local legislation.
Product Name
RAID COMMERCIAL INSECTICIDE RESIDUAL SURFACE SPRAY
14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
Shipping Name
Subsidiary Risk(s)
Packing Group
Hazchem Code
Shipping Name
Subsidiary Risk(s)
Packing Group
Shipping Name
Subsidiary Risk(s)
Packing Group
15. REGULATORY INFORMATION
Poison Schedule

A poison schedule number has not been allocated to this product using the criteria in the Standard for the UniformScheduling of Drugs and Poisons (SUSDP).
All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION
Additional
SYNERGISM - ANTAGONISM: Ingredients in this product may act together to aggravate or reduce adverse Information
effects. Accordingly the time weighted average concentration (TWA) provided for single ingredients should beconsidered as a guide only and all due care exercised when handling.
AEROSOL CANS may explode at temperatures approaching 50°C.
ABBREVIATIONS:ACGIH - American Conference of Industrial Hygienists.
ADG - Australian Dangerous Goods.
BEI - Biological Exposure Indice(s).
CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds.
CNS - Central Nervous System.
EC No - European Community Number.
HSNO - Hazardous Substances and New Organisms.
IARC - International Agency for Research on Cancer.
mg/m³ - Milligrams per Cubic Metre.
NOS - Not Otherwise Specified.
pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).
ppm - Parts Per Million.
RTECS - Registry of Toxic Effects of Chemical Substances.
STEL - Short Term Exposure Limit.
SWA - Safe Work Australia.
TWA - Time Weighted Average.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factors including: frequencyand duration of use; quantity used; effectiveness of control measures; protective equipment used and method ofapplication. Given that it is impractical to prepare a ChemAlert report which would encompass all possiblescenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only.
Product Name
RAID COMMERCIAL INSECTICIDE RESIDUAL SURFACE SPRAY
Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protective equipment ismade.
Report Status
This document has been compiled by RMT on behalf of the manufacturer of the product and serves as themanufacturer's Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer orobtained from third party sources and is believed to represent the current state of knowledge as to the appropriatesafety and handling precautions for the product at the time of issue. Further clarification regarding any aspect ofthe product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provideany warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss,injury or damage (including consequential loss) which may be suffered or incurred by any person as aconsequence of their reliance on the information contained in this SDS.
Prepared By
Risk Management Technologies5 Ventnor Ave, West PerthWestern Australia 6005Phone: +61 8 9322 1711Fax: +61 8 9322 1794Email: info@rmt.com.auWeb: www.rmt.com.au SDS Date 03 Nov 2011
End of Report

Source: http://www.apackcommercial.com.au/blog/wp-content/uploads/2012/07/MSDS-Raid-Residual.pdf

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