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Hazard Alert Code:
X-DUTY CLEANER
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: X-DUTY CLEANER
PRODUCT USE
Cleaner for tile, stone, paving and grout.
SUPPLIER
Address:1201 Orange Street, Suite 600 One Commerce CenterWillmingtonDE, 19801 USATelephone: +1 866 667 5119Telephone: +61 2 9954 3211Emergency Tel: Outside USA +1 (813) 248 0585Emergency Tel: CHEM-TEL (800) 255-3924Fax: +61 2 9954 3162 HAZARD RATINGS
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
RISK SAFETY
Irritating to eyes and skin.
Do not breathe gas/ fumes/ vapour/ spray. May cause SENSITISATION by skin contact. Very toxic to aquatic organisms may cause long-term adverse Keep container in a well ventilated place. effects in the aquatic environment. HARMFUL - May cause lung damage if swallowed. Avoid exposure - obtain special instructions before use. To clean the floor and all objects contaminated by this material use Vapours may cause drowsiness and dizziness. Inhalation skin contact and/or ingestion may produce health Cumulative effects may result following exposure*. This material and its container must be disposed of in a safe way. May produce discomfort of the respiratory system*. Keep away from food drink and animal feeding stuffs. Limited evidence of a carcinogenic effect*. Take off immediately all contaminated clothing. In case of contact with eyes rinse with plenty of water and contact Doctor or Poisons Information Centre. If swallowed IMMEDIATELY contact Doctor or Poisons Information Centre (show this container or label). Use appropriate container to avoid environment contamination. Avoid release to the environment. Refer to special instructions/ safety data sheets. Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
SWALLOWED
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Hazard Alert Code:
X-DUTY CLEANER
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) „ If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent „ Observe the patient carefully. „ Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. „ Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. „ Seek medical advice. EYE
If this product comes in contact with the eyes:
„ Immediately hold eyelids apart and flush the eye continuously with running water. „ Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the „ Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. „ Transport to hospital or doctor without delay. „ Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. SKIN
If skin contact occurs:
„ Immediately remove all contaminated clothing, including footwear. „ Flush skin and hair with running water (and soap if available). „ Seek medical attention in event of irritation. „ If fumes or combustion products are inhaled remove from contaminated area. „ Lay patient down. Keep warm and rested. „ Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. „ Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as NOTES TO PHYSICIAN
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
„ Water spray or fog. „ Foam. „ Dry chemical powder. „ BCF (where regulations permit). „ Carbon dioxide. FIRE FIGHTING
„ Alert Fire Brigade and tell them location and nature of hazard. „ Wear breathing apparatus plus protective gloves. „ Prevent, by any means available, spillage from entering drains or water course. „ Use water delivered as a fine spray to control fire and cool adjacent area. „ Avoid spraying water onto liquid pools. „ Do not approach containers suspected to be hot. „ Cool fire exposed containers with water spray from a protected location. „ If safe to do so, remove containers from path of fire. FIRE/EXPLOSION HAZARD
„ Combustible. „ Slight fire hazard when exposed to heat or flame. „ Heating may cause expansion or decomposition leading to violent rupture of containers. „ On combustion, may emit toxic fumes of carbon monoxide (CO). „ May emit acrid smoke. „ Mists containing combustible materials may be explosive. Other combustion products include:.
carbon dioxide (CO2).
nitrogen oxides (NOx).
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
„ Remove all ignition sources. „ Clean up all spills immediately. „ Avoid breathing vapours and contact with skin and eyes. „ Control personal contact by using protective equipment. „ Contain and absorb spill with sand, earth, inert material or vermiculite. „ Wipe up. „ Place in a suitable labelled container for waste disposal. http://full.chemwatch.net/chemgold/msds.exe?fontsize=&print=Y&rCode=N&prefna.
Hazard Alert Code:
X-DUTY CLEANER
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) „ Clear area of personnel and move upwind. „ Alert Fire Brigade and tell them location and nature of hazard. „ Wear breathing apparatus plus protective gloves. „ Prevent, by any means available, spillage from entering drains or water course. „ No smoking, naked lights or ignition sources. „ Increase ventilation. „ Stop leak if safe to do so. „ Contain spill with sand, earth or vermiculite. „ Collect recoverable product into labelled containers for recycling. „ Absorb remaining product with sand, earth or vermiculite. „ Collect solid residues and seal in labelled drums for disposal. „ Wash area and prevent runoff into drains. „ If contamination of drains or waterways occurs, advise emergency services. SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
O: May be stored together with specific preventions Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
Avoid generating and breathing mist.
„ Avoid all personal contact, including inhalation. „ Wear protective clothing when risk of exposure occurs. „ Use in a well-ventilated area. „ Prevent concentration in hollows and sumps. „ DO NOT enter confined spaces until atmosphere has been checked. „ Avoid smoking, naked lights or ignition sources. „ Avoid contact with incompatible materials. „ When handling, DO NOT eat, drink or smoke. „ Keep containers securely sealed when not in use. „ Avoid physical damage to containers. „ Always wash hands with soap and water after handling. „ Work clothes should be laundered separately. „ Use good occupational work practice. „ Observe manufacturer's storing and handling recommendations. „ Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions. SUITABLE CONTAINER
„ Metal can or drum „ Packaging as recommended by manufacturer. „ Check all containers are clearly labelled and free from leaks. STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
„ Store in original containers. „ Keep containers securely sealed. „ No smoking, naked lights or ignition sources. „ Store in a cool, dry, well-ventilated area. „ Store away from incompatible materials and foodstuff containers. „ Protect containers against physical damage and check regularly for leaks. „ Observe manufacturer's storing and handling recommendations. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
The following materials had no OELs on our records http://full.chemwatch.net/chemgold/msds.exe?fontsize=&print=Y&rCode=N&prefna.
Hazard Alert Code:
X-DUTY CLEANER
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) • d-limonene: CAS:5989-27-5 CAS:138-86-3 MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
N-METHYL-2-PYRROLIDONE:
Reports of skin and eye irritation and chronic headaches have been
reported in workers exposed to 1-methyl-2-pyrrolidone. The Australian ES
is based on a 10-fold uncertainty factor of the no-observable-adverse-
effect level (NOAEL) of 24 ppm where adverse respiratory effects were
observed in a 4-week inhalation study in rats.
D-LIMONENE:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically
occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation
and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-
observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach,
typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from
irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a
five-category system based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be
consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to
that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can: „ cause inflammation „ cause increased susceptibility to other irritants and infectious agents „ lead to permanent injury or dysfunction „ permit greater absorption of hazardous substances and „ acclimate the worker to the irritant warning properties of these substances thus increasing the risk of overexposure. CEL TWA: 30 ppm, 165.6 mg/m3 (compare WEEL-TWA*)
A Workplace Environmental Exposure Level* has been established by AIHA
(American Industrial Hygiene Association) who have produced the following
rationale:
D-limonene is not acutely toxic. In its pure form it is not a sensitiser
but is irritating to the skin. Although there is clear evidence of
carcinogenicity in male rats, the effect has been attributed to an
alpha-2u-globin (a2u-G) renal toxicity which is both species and gender
specific. Humans do not synthesise a2u-G, and metabolism studies indicate
that 75% to 95% of d-limonene is excreted in 2-3 days with different
metabolites identified between humans and rats. In a 2-year study, liver
effects were noted in male mice at 500 mg/kg and reduced survival was noted
in female rats at 600 mg/kg. The no observable effect levels (NOELs) were
250 and 300 mg/kg, respectively. A WEEL of 30 ppm is recommended to
protect against these effects.
PERSONAL PROTECTION
„ Safety glasses with side shields; or as required, „ Chemical goggles. „ Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59] HANDS/FEET
DO NOT use this product to clean the skin.
OTHER
„ Overalls. „ Barrier cream „ Eyewash unit. ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection. Provide adequateventilation in warehouse or closed storage areas. http://full.chemwatch.net/chemgold/msds.exe?fontsize=&print=Y&rCode=N&prefna.
Hazard Alert Code:
X-DUTY CLEANER
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Very light yellow, clear liquid with solvent odour; dispersible in water. USA VOC content: < 20 g/litre PHYSICAL PROPERTIES
Volatile Component (%vol): Not available Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available Decomposition Temp (°C): Not available. Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
„ Product is considered stable. „ Hazardous polymerisation will not occur. Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical
pneumonitis.
EYE
The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
SKIN
Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.
The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness,
swelling, the production of vesicles, scaling and thickening of the skin. Repeated exposures may produce severe ulceration.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation.
INHALED
The vapour is discomforting.
Inhalation of vapour is more likely at higher than normal temperatures.
Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with
headache and dizziness, slowing of reflexes, fatigue and inco-ordination.
Not considered an irritant through normal use.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational
Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.
Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS].
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
CARCINOGEN IARC: International Agency for Research on Cancer (IARC) Carcinogens: d-limonene Category: The substance is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in animal testing. Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways. Refer to data for ingredients, which follows: N-METHYL-2-PYRROLIDONE: DO NOT discharge into sewer or waterways. log Kow: -0.44-0.1 D-LIMONENE: http://full.chemwatch.net/chemgold/msds.exe?fontsize=&print=Y&rCode=N&prefna.
Hazard Alert Code:
X-DUTY CLEANER
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do notcontaminate water when cleaning equipment or disposing of equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites. Substances containing unsaturated carbons are ubiquitous in indoor environments. They result from many sources (see below). Mostare reactive with environmental ozone and many produce stable products which are thought to adversely affect human health.Thepotential for surfaces in an enclosed space to facilitate reactions should be considered. Major Stable Products produced following Methacrolein, methyl vinyl ketone, nitrogen dioxide, acetone, 6MHQ, geranyl acetone, unsaturated sterols, oleic acid and other oxo-nonanoic acid, azelaic acid, nonanoic Formaldehyde, 4-AMC, pinoaldehyde, pinic 4-Phenylcyclohexene, 4-vinylcyclohexene, Formaldehyde, acetaldehyde, styrene, 2-ethylhexyl acrylate, unsaturated benzaldehyde, hexanal, nonanal, 2-nonenal Propanal, hexanal, nonanal, 2-heptenal, 2- Formaldehyde, acetaldehyde, glycoaldehyde, formic acid, acetic acid, hydrogen and organic peroxides, acetone, Certain cleaning products, polishes, waxes, alpha-terpineol, linalool, linalyl acetate and benzaldehyde, 4-hydroxy-4-methyl-5- (3H)-furanone, 4-AMC, SOAs including ultrafine particles Formaldehyde, methacrolein, methyl vinyl Photocopier toner, printed paper, styrene Squalene, unsaturated sterols, oleic acid nonanoic acid, azelaic acid, nonanoic acid Unsaturated fatty acids from plant waxes, aldehydes; azelaic acid; nonanoic acid; 9- leaf litter, and other vegetative debris; soot; oxo-nonanoic acid and other oxo-acids; diesel particles compounds with mixed functional groups (=O, -OH, and -COOH) Oxidized polycyclic aromatic hydrocarbons Perfumes, colognes, essential oils (e.g. Limonene, alpha-pinene, linalool, linalyl hydroxy-4-methyl-5-hexen-1-al, 5-ethenyl- acetate, terpinene-4-ol, gamma-terpinene dihydro-5-methyl-2(3H) furanone, SOAs including ultrafine particles Formaldehyde, 4-AMC, pinonaldehyde, acetone, pinic acid, pinonic acid, formic acid, benzaldehyde, SOAs including ultrafine particles Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA, 4-oxopentanal, SOA, Secondary Organic Aerosols Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006. Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.). The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of waters after release in calm sea conditions.
This is expected to evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy radicals. Some of the material will become associated with benthic sediments, and it is likely to be spread over a fairly wide area of sea floor.
Marine sediments may be either aerobic or anaerobic. The material, in probability, is biodegradable, under aerobic conditions(isomerised olefins and alkenes show variable results). Evidence also suggests that the hydrocarbons may be degradable underanaerobic conditions although such degradation in benthic sediments may be a relatively slow process. Under aerobic conditions the material will degrade to water and carbon dioxide, while under anaerobic processes it will produce water,methane and carbon dioxide. Based on test results, as well as theoretical considerations, the potential for bioaccumulation may be high. Toxic effects are oftenobserved in species such as blue mussel, daphnia, freshwater green algae, marine copepods and amphipods. DO NOT discharge into sewer or waterways. LD50 Colinus virginianus (Bobwhite quail, 16 weeks old) oral >2000 mg/kg http://full.chemwatch.net/chemgold/msds.exe?fontsize=&print=Y&rCode=N&prefna.
Hazard Alert Code:
X-DUTY CLEANER
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) LC50 Colinus virginianus (Bobwhite quail, 10 day old) dietary >5620 ppm/8 days LC50 Colinus virginianus (Bobwhite quail, 14 day old) dietary >5000 ppm/8 days LC50 Anas platyrhynchos (Mallard duck, 14 day old) dietary >5000 ppm/8 days LC50 Oncorhynchus mykiss (Rainbow trout) 80 ppm/96 hr (95% confidence limit: 71.4-88.7 ppm); static /92% AI formulated product LC50 Oncorhynchus mykiss (Rainbow trout) 568 ppm/96 hr (95% confidence limit: 437-852 ppm); static /4.0% AI formulated product EC50 Daphnia magna (Water flea, <24 hr old; intoxication, immobilization) 17 ppm/48 hr (95% confidence limit: 11-33 ppm); static /4.0% AI formulated product LC50 Pimephales promelas (Fathead minnow) 966 ppm/96 hr (95% confidence limit: 740-1652 ppm); static /4.0% AI formulated product LC50 Pimephales promelas (Fathead minnow) 38.5 mg/L/96 hr; flow through /from table/ LC50 Leuciscus idus (Golden orfe) 32 mg/L/48 hr /Conditions of bioassay not specified in source examined The acute toxicity of d-limonene ranges from slight to high for aquatic organisms. The lowest acute toxicity values (EC50 or LC50)identified were approximately 0.4 mg/litre for Daphnia (US EPA, 1990b) and 0.7 mg/litre for fish (US EPA, 1990a,b). The no-observed-effect concentration (NOEC) for green algae is approximately 4 mg/litre (US EPA, 1990a). The acute toxicity (EC50 or LC50) of dipentene to Daphnia and fish is about50-70 times lower than that for d-limonene (US EPA, 1990b). No studies were identified on the chronic toxicity of limonene to aquaticorganisms. Section 13 - DISPOSAL CONSIDERATIONS
„ Consult manufacturer for recycling options and recycle where possible . „ Consult State Land Waste Management Authority for disposal. „ Incinerate residue at an approved site. „ Recycle containers if possible, or dispose of in an authorised landfill. Section 14 - TRANSPORTATION INFORMATION
Labels Required: COMBUSTIBLE LIQUID (bulk storage only)
HAZCHEM:
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA, IMDG Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
X- Duty Cleaner (CAS: None):
No regulations applicable
N- methyl- 2- pyrrolidone (CAS: 872- 50- 4) is found on the following regulatory
lists;
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Schedule 6
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume
List
OECD Representative List of High Production Volume (HPV) Chemicals
d- limonene (CAS: 5989- 27- 5) is found on the following regulatory lists; Australia Inventory of Chemical Substances (AICS) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6 International Agency for Research on Cancer (IARC) Carcinogens OECD Representative List of High Production Volume (HPV) Chemicals OSPAR List of Substances of Possible Concern d- limonene (CAS: 138- 86- 3) is found on the following regulatory lists; Australia Inventory of Chemical Substances (AICS) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6 IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk OECD Representative List of High Production Volume (HPV) Chemicals No data available for N- methyl- 2- pyrrolidone as CAS: 26138- 58- 9. Section 16 - OTHER INFORMATION
Ingredients with multiple CAS Nos
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Hazard Alert Code:
X-DUTY CLEANER
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) REPRODUCTIVE HEALTH GUIDELINES
These exposure guidelines have been derived from a screening level of risk assessment and should not be construed as unequivocally safe limits. ORGS represent an 8-hour time -weighted average unless specified otherwise. CR = Cancer Risk/10000; UF = Uncertainty factor: TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of vapour components/concentrations: Composite Exposure Standard for Mixture (TWA)
(mg/m3): 165.6 mg/m³ If the breathing zone concentration of ANY of the components listed below is exceeded, "Worst Case"
considerations deem the individual to be overexposed. Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
Operations which produce a spray/mist or fume/dust, introduce particulates to the breathing zone. If the breathing zone concentrationof ANY of the components listed below is exceeded, "Worst Case" considerations deem the individual to be overexposed. At the"Composite Exposure Standard for Mixture" (TWA) (mg/m3): 165.6 mg/m³ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700. http://full.chemwatch.net/chemgold/msds.exe?fontsize=&print=Y&rCode=N&prefna.

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